No, Filo can only be directly connected with your smartphone. You can use your smartwatch app to interact quickly with your Filo, without having to go through your smartphone each time.
Attention: your Filo(s) will only show up as in range if they are close to your smartphone and out of range if they are far from the phone. The smartwatch allows you only to interact more quickly with your Filo but the connection runs only between Filo and your smartphone. The smartwatch is an extension of the app from your smartphone.